N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate
نویسندگان
چکیده
In the title salt, C16H24N4 (2+)·2NO3 (-), both the cation and anion are placed in general positions, although the cation displays non-crystallographic inversion symmetry, with the aliphatic chain extended in an all-trans conformation. The benzene rings are almost parallel, with a dihedral angle between their mean planes of 3.3 (6)°. The nitrate ions are placed in the vicinity of the protonated amine groups, forming efficient N-H⋯O inter-ion hydrogen bonds. Each nitrate ion in the asymmetric unit bridges two symmetry-related cations, forming an R 4 (4)(18) ring, a common motif in organic ammonium nitrate salts. This results in the formation of chains along [010] with alternating cations and anions. The neutral amine groups are involved in slightly weaker N-H⋯O hydrogen bonds with the nitrate O atoms, and there are also a number of C-H⋯O hydrogen bonds present. The resulting supra-molecular structure is based on a two-dimensional network extending in the ab plane.
منابع مشابه
Design, Characterization and Application of N1,N1,N2,N2-Tetramethyl-N1,N2-bis(sulfo)ethane-1,2-diaminium Trifluoroacetate as a Novel Ionic-Liquid Catalyst for the Production of Polyhydroquinolines
A novel Brønsted acidic ionic liquid namely N1,N1,N2,N2-tetramethyl-N1,N2-bis(sulfo)ethane-1,2-diaminium trifluoroacetate {[TMBSED][TFA]2} was synthesized, and characterized by studying its1H NMR, 13C NMR, 19F NMR and mass spectral data. Afterward, the ionic liquid was applied ascatalyst for the production of polyhydroquinoline derivatives via the one-pot multi-componentreaction of arylaldehyde...
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013